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Microsoft publishes many great overview articles on migrations, more specifically, about the question you are asking. Since this is a general question, I would like to point you to this particular TechNet overview article from Microsoft: How to migrate from Exchange 5.5 to Exchange 2003 using the Active Directory Migration Tool.
Do you have comments on this Ask the Expert Q&A? Let us know.
Related information from SearchExchange.com:
Expert Roundup: Solving Exchange Migration Challenges
Article: Collaboration tools seek to ease migration woes
Expert Advice: Missing public folders after migration
11 tips in 11 minutes: Migrating from Exchange 5.5 to Exchange 2003
Learning Guide: Exchange migration
Reference Center: Exchange Server migration advice and resources
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