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You should have a look at LDIFDE. See Microsoft Knowledge Base Article 237677: Using LDIFDE to import and export directory objects to Active Directory for instructions on how to make these changes. You'll need to be creative in Excel (or Access) in order to match up the source data from Human Resources with Active Directory data using some unique primary key.
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Glossary: Lightweight Directory Access Protocol (LDAP)
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Reference Center: Active Directory tips and resources
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