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You only mention one Exchange server, yet there are two URLs. Is there also a front-end server that the clients have to go through from the Internet? If so, then the certificate must be applied to the front-end server, not the server with mailboxes on it.
A well documented issue with the Pocket PC 2002 operating systems is that, if you are going to establish an HTTPS connection, the device must explicitly trust the Root certificate authority (CA). If you are running a Windows CA, and not using a third-party like VeriSign, then the Pocket PC will not trust your root CA without some additional work. See Sample to add root certificates to Pocket PC 2002.
According to Microsoft, this is not an issue with Pocket PC 2003. I don't think this is your problem though, because you are working internally without any errors.
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Related information from SearchExchange.com:
Reference Center: Mobile and wireless resources
Reference Center: User authentication tips and resources
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