Next, double-click the mail icon, then click on Show Profiles. From there, either select Add to create a new profile, Copy to copy an existing profile to use as a starting point or Properties to modify an existing profile.
To access the mail icon directly, you may also be able to create a shortcut to mlcfg32.cpl, which is in the C:\Program Files(x86)\Microsoft Office\Office12\ directory.
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This was first published in December 2009