Nevertheless, should you want to do this, the first step is taking a look at Event ID 1221 in the server's Application...
Event Log for that store. it will tell you whether there is enough free space in the store. If there isn't much free space, I wouldn't recommend doing it.
If you've determined there's enough free space in the store and you need to reclaim disk space, the command is:
Dig Deeper on Microsoft Exchange Server Defragmentation
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