Nevertheless, should you want to do this, the first step is taking a look at Event ID 1221 in the server's Application...
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Event Log for that store. it will tell you whether there is enough free space in the store. If there isn't much free space, I wouldn't recommend doing it.
If you've determined there's enough free space in the store and you need to reclaim disk space, the command is:
Dig Deeper on Microsoft Exchange Server Defragmentation
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